Morphology of drawn syndiotactic polypropylene films

Morphological studies were conducted to investigate the drawability of melt-quenched (MQ) and slowly cooled (MSC) films of syndiotactic polypropylene (sPP) with a high syndiotactic pentad fraction. Transmission electron microscopy (TEM) using the ruthenium tetraoxide staining and ultrathin sectioning method revealed that amorphous chains as the matrix of MQ film played a role in drawability of the film by their alignment to machine direction (MD) and partial crystallizations into nanofibrils. On the other hand, the initial strain induced, rotations of clusters of long lamellar crystals as the major entity of MSC film accompanying breaks of long lamellae and formation of crazes and microvoids at the cluster boundary. Compared with a homogeneous thinning of MQ film by drawing, ca. 100 nm-thick layer slips along MD and parallel to the film surface took place in MSC film. This gave rise to the formation of V-shaped bent lamellar morphology and their further break into a smaller cluster of stacked lamellae which were aligned oblique by ca. 35 from MD. With elongation, some nanofibrils formed from chains generated by the partial breaks of lamellae are aligned perpendicular to the remained oblique lamellae and others parallel to MD in region where lamellar morphology almost disappeared. No chain slips in the nanofibrils can be related to a low elongation at break, i.e. a low ductility of sPP films. The lower elongation at break for MSC film than for MQ one can be interpreted by microvoids initially formed in the neck region and later moved to the fully drawn part, the microvoids initiating the break of the drawn film

Exclusion of soil macrofauna did not affect soil quality but increased crop yields in a sub-humid tropical maize-based system

Soil macrofauna such as earthworms and termites are involved in key ecosystem functions and thus considered important for sustainable intensification of crop production. However, their contribution to tropical soil and crop performance, as well as relations with agricultural management (e.g. Conservation Agriculture), are not well understood. This study aimed to quantify soil macrofauna and its impact on soil aggregation, soil carbon and crop yields in a maize-soybean system under tropical sub-humid conditions. A field trial was established in Western Kenya in 2003 with tillage and residue retention as independent factors. A macrofauna exclusion experiment was superimposed in 2005 through regular insecticide applications, and measurements were taken from 2005 to 2012. Termites were the most abundant macrofauna group comprising 61% of total macrofauna numbers followed by ants (20%), while few earthworms were present (5%). Insecticide application significantly reduced termites (by 86 and 62%) and earthworms (by 100 and 88%) at 0-15 and 15-30 cm soil depth respectively. Termite diversity was low, with all species belonging to the family of Macrotermitinae which feed on wood, leaf litter and dead/dry grass. Seven years of macrofauna exclusion did not affect soil aggregation or carbon contents, which might be explained by the low residue retention and the nesting and feeding behavior of the dominant termites present. Macrofauna exclusion resulted in 34% higher maize grain yield and 22% higher soybean grain yield, indicating that pest damage – probably including termites - overruled any potentially beneficial impact of soil macrofauna. Results contrast with previous studies on the effects of termites on plant growth, which were mostly conducted in (semi-) arid regions. Future research should contribute to sustainable management strategies that reduce detrimental impact due to dominance of potential pest species while conserving soil macrofauna diversity and their beneficial functions in agroecosystems

A Comparison of Some Fuzzy Relation-based Linguistic Preference Models for Multiple-Factor Project Assessment

Some approaches to the use of linguistic-preference models based on fuzzy relations in the context of multiple factor project assessment are considered. Projects are characterized in terms of linguistic expressions of 'performance' with respect to factors or impacts and the 'importance' of those factors and impacts. Some variations of methods by Wilhelm and Parsaei (1991) and Eldukair and Ayyub (1992) are considered with some possible analogous methods. A simple illustrative, hypothetical example is developed to compare methods in the context of a proposed bridge river crossing in the city of Brisbane, Queensland, Australia, assessed against six factors: (1) cost, (2) lifespan, (3) usage, (4) aesthetics, (5) construction time, and (6) environmental impact

Suitability Mapping of Solar Energy Potential of Selected Areas in Camarines Sur using ArcGIS

Abstract— Solar energy, the most common and scalable renewable energy, has a huge potential to supply the increasing electricity demand. Hence, proper site selection for deploying solar PV systems is required. This paper presents the development of a solar suitability map to identify potential sites for solar PV systems in the selected areas in the Rinconada District of the province of Camarines Sur, Philippines. ArcGIS analyzed the annual average solar radiation, weather datasets, and geographical conditions and performed suitability mapping combined with the Analytic Hierarchy Process (AHP) to identify the weights of the nine criteria of suitable site selection. Based on these factors, twenty-seven (27) barangays were found suitable, where the central and eastern parts of Barangay Malawag in Nabua and a massive part of Barangay Causip in Bula are the most suitable locations for large-scale solar PV installation

Do UK universities communicate their brands effectively through their websites?

This paper attempts to explore the effectiveness of UK universities’ websites. The area of branding in higher education has received increasing academic investigation, but little work has researched how universities demonstrate their brand promises through their websites. The quest to differentiate through branding can be challenging in the university context, however. It is argued that those institutions that have a strong distinctive image will be in a better position to face a changing future. Employing a multistage methodology, the web pages of twenty UK universities were investigated by using a combination of content and multivariable analysis. Results indicated ‘traditional values’ such as teaching and research were often well communicated in terms of online brand but ‘emotional values’ like social responsibility and the universities’ environments were less consistently communicated, despite their increased topicality. It is therefore suggested that emotional values may offer a basis for possible future online differentiation

Interactions between dietary docosahexaenoic acid and other long-chain polyunsaturated fatty acids on performance and fatty acid retention in post-smolt Atlantic salmon (Salmo salar)

A study with varying dietary inclusion levels (1, 5, 10, 15 and 20 g kg-1) of docosahexaenoic acid (DHA; 22:6n-3) was conducted with post-smolt (111 ± 2.6 g; mean ± S.) Atlantic salmon (Salmo salar) over a 9-week period. In addition to the series of DHA inclusion levels, the study included further diets that had DHA at 10 g kg-1 in combination with either eicosapentaenoic acid (EPA; 20:5n-3) or arachidonic acid (ARA; 20:4n-6), both also included at 10 g kg-1. An additional treatment with both EPA and DHA included at 5 g kg-1 (total of 10 g kg-1 long-chain polyunsaturated fatty acids, LC-PUFA) was also included. After a 9-week feeding period, fish were weighed, and carcass, blood and tissue samples collected. A minor improvement in growth was seen with increasing inclusion of DHA. However, the addition of EPA further improved growth response while addition of ARA had no effect on growth. As with most lipid studies, the fatty acid composition of the whole body lipids generally reflected that of the diets. However, there were notable exceptions to this, and these implicate some interactions among the different LC-PUFA in terms of the fatty acid bio- chemistry in this species. At very low inclusion levels, DHA retention was substantially higher (*250 %) than that at all other inclusion levels (31–58 %). The inclusion of EPA in the diet also had a positive effect on the retention efficiency of DHA. However, EPA retention was highly variable and at low DHA inclusion levels there was a net loss of EPA as this fatty acid was most likely elongated to produce DHA, consistent with increased DHA retention with addi- tional EPA in the diet. Retention of DPA (22:5n-3) was high at low levels of DHA, but diminished with increasing DHA inclusion, similar to that seen with DHA retention. The addition of EPA to the diet resulted in a substantial increase in the efficiency of DPA retention; the inclusion of ARA had the opposite effect. Retention of ARA was unaffected by DHA inclusion, but the addition of either EPA or ARA to the diet resulted in a substantial reduction in the efficiency of ARA retention. No effects of dietary treatment were noted on the retention of either linolenic (18:3n-3) or linoleic (18:2n-6) acids. When the total n-3 LC-PUFA content of the diet was the same but consisted of either DHA alone or as a combination of EPA plus DHA, the performance effects were similar

Complex X chromosome rearrangement associated with multiorgan autoimmunity

BACKGROUND: Turner syndrome, a congenital condition that affects 1/2,500 births, results from absence or structural alteration of the second sex chromosome. Turner syndrome is usually associated with short stature, gonadal dysgenesis and variable dysmorphic features. The classical 45,X karyotype accounts approximately for half of all patients, the remainder exhibit mosaicism or structural abnormalities of the X chromosome. However, complex intra-X chromosomal rearrangements involving more than three breakpoints are extremely rare. RESULTS: We present a unique case of a novel complex X chromosome rearrangement in a young female patient presenting successively a wide range of autoimmune diseases including insulin dependent diabetes mellitus, Hashimoto's thyroiditis, celiac disease, anaemia perniciosa, possible inner ear disease and severe hair loss. For the genetic evaluation, conventional cytogenetic analysis and FISH with different X specific probes were initially performed. The complexity of these results and the variety of autoimmune problems of the patient prompted us to identify the exact composition and breakpoints of the rearranged X as well as methylation status of the X chromosomes. The high resolution array-CGH (assembly GRCh37/hg19) detected single copy for the whole chromosome X short arm. Two different sized segments of Xq arm were present in three copies: one large size of 80,3 Mb from Xq11.1 to Xq27.3 region and another smaller (11,1 Mb) from Xq27.3 to Xq28 region. An 1,6 Mb Xq27.3 region of the long arm was present in two copies. Southern blot analysis identified a skewed X inactivation with approximately 70:30 % ratios of methylated/unmethylated fragments. The G-band and FISH patterns of the rearranged X suggested the aspect of a restructured i(Xq) chromosome which was shattered and fortuitously repaired. The X-STR genotype analysis of the family detected that the patient inherited intact maternal X chromosome and a rearranged paternal X chromosome. The multiple Xq breakages and fusions as well as inverted duplication would have been expected to cause a severe Turner phenotype. However, the patient lacks many of the classic somatic features of Turner syndrome, instead she presented multiorgan autoimmune diseases. CONCLUSIONS: The clinical data of the presented patient suggest that fragmentation of the i(Xq) chromosome elevates the risk of autoimmune diseases